5th attachmentThis is the equation representing the formation of propanoic acid.
3C + 3H2 + 1/2O2 ----> C3H5OHSince the enthalpy changes of combustion has been given to you, you also need to write the equation relating each substance and its respective combustion.
1. C + O
2 ----> CO
2 (Enthalpy change of formation of carbon dioxide)
2. H
2 + 0.5O
2 ----> H
2O (Enthalpy change of formation of water)
3. C
3H
5OH + 9/2O
2 ----> 3CO
2 + 3H
2O (Enthalpy change of combustion of propanoic acid)
As you may observe, the combustion of both hydrogen and carbon leads to carbon dioxide and hydrogen as well as the combustion of butane.
Hence, according to Hess's law, we may opt for another route in the conversion of carbon and hydrogen to butane.
Let's say we'll convert 3 moles of carbon and 3 moles of Hydrogen gas to carbon dioxide and water. Then these two products are converted to propanoic acid.
In practise these reactions are not feasible. But in theory we may opt for that method to find standard enthalpy changes of a particular reaction.
Let ^C be the enthalpy change of combustion of carbon.
So Enthalpy change of formation of propanoic acid = 3(^C) + 3(^H) - (^C
3H
5OH) = 3(-393.5) + 3(-285.
- (-1527.2) =
-510.7 KJNOTE : We need to subtract the enthalpy change of combustion since we are converting carbon dioxide and water back to propanoic acid whereas the enthalpy change of combustion of propanoic acid actually is the energy evolved when 1 mole of propanoic acid is completely burnt to carbon dioxide and water. In other words we are doing just the contrary, that's why we need to subtract it.