First you should write the equation showing the solubility of the salt.
In the first case it's Pb
2C
2O
4 -----> Pb
2+ + C
2O
42-Now you can write the K
spKs
p = [Pb
2+][C
2O
42-]
Since mole ratio of the two ions formed is
1:1, we can take it to be
:
So K
sp =
2 = 8.5 x 10
-9Now you just have to find the value of
.
I'll let you try the 2nd one yourself. If you can't do tell me and i'll try to be clearer