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Branching tends to lower the boiling point since the branching decreases the surface area. Also, straight chain alkanes tend to bind to one another better, so their boiling points are usually higher.
Haloalkanes- Their boiling points are higher than the corresponding alkanes and increase with the atomic weight and increasing no. of halides. This is because the intermolecular forces increase as a result of dipole-dipole interaction because of increased polarity.
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