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GPE: energy due to position.
KE: energy due to motion.
So at start, GPE is greatest (no motion). When thrown up (GPE converted to KE) then momentarily stops at top of flightpath (GPE again) then when it drops (GPE to KE increases), so just before it hits, KE is greatest, therefore a lot of GPE has been converted, therefore GPE is least. Got it?