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Help in AS Chemistry!

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ruby92:
m/j 2009 variant 1
4 b iii  ??? ???

moon:
Can somebody help me in solving question no. 4(c) in June 2001 ppr 2?? Thanks in advance.

TJ-56:
please can someone confirm if its an error made in the mark scheme about mj 06 q4 (f) (ii)
where did the carbon atom in the middle go??
Thanks for any help

sweetie:

--- Quote from: TJ-56 on May 30, 2010, 05:07:15 pm ---please can someone confirm if its an error made in the mark scheme about mj 06 q4 (f) (ii)
where did the carbon atom in the middle go??
Thanks for any help

--- End quote ---

i have da same Q., plzzzzzzzzzzzzz  sum1 help

yinyang:

--- Quote from: TJ-56 on May 30, 2010, 05:07:15 pm ---please can someone confirm if its an error made in the mark scheme about mj 06 q4 (f) (ii)
where did the carbon atom in the middle go??
Thanks for any help

--- End quote ---

the formula of the allyl alcohol is CH2=CHCH2OH

when this allyl alcohol is heated under reflux with acidified MnO4-  the double bond breaks

so you will have   CH2O   and     COHCH2OH

since it is heated under reflux the products are further oxidised

CH2O  ------->    2CO2  + 2H2O




COHCH2OH  -------->       HO2CCO2H


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