This is a part of green chemistry.
Biofuels, mainly ethanol and other alchohols, are all carbon compunds, and thus release carbon-dioxide into the atmosphere.
Also, the cost to produce them, such as tactors, harvesters, irrigation all take up fuel.
Now large scale production will mainly cause food prices to rise.
For the last question, you have to give me the stats on each of them.
Hope that helps.