Qualification > Sciences
ANY HELP! 2!
Saladin:
PPL THE DUDE IS BAQ
POST ANY DOUBTS AND ME OR NID WILL HELP U ANSA DEM! ;D
mousa:
can you plz explain this and as to why they are correct??
The conversion of graphite into diamond is an endothermic reaction (?H = +3 kJ mol–1).
C(graphite) ? C(diamond)
Which statements are correct?
1 The enthalpy change of atomisation of diamond is smaller than that of graphite.
2 The bond energy of the C–C bonds in graphite is greater than that in diamond.
3 The enthalpy change of combustion of diamond is greater than that of graphite
the markin scheme says that all of them are correct..
mousa:
and ya explain electropositivity... :)
Saladin:
Electopositivity is the oppsosite of electronegativity. It is an element's ability to donate electrons electrons. Basically how easily something can donate electrons, and thus shows metallic character. For example, Cs is very electro-positive. It has the best ability to donate electrons. But Chlorine is not electropositive, it is electronegative and will want to pull electrons to itself.
Diamond and Graphite:
In order for this reaction to endothermic, 1 2 and 3 must be true.
2 must be true because the bonds broken (3 c-c) must have a greater bond energy than 4 c-c bonds in diamond, in order for more energy to required than given out, for the reaction to be endothermic. Becasue 3 C-C bonds are broken and 4 C-C bonds are made.
1 therefore must be true because atomisation means turning it into gaseous form, thus breaking 3C-C bonds, thus 1 is the same as 2.
3: An endothermic reaction means the material formed is less stable than its products. Thus, the enthalpy change of burning diamond should be greater than graphite, as diamond is less stable and will lose more energy than graphite.
Hope this asnwers ur q. This is by far one of the hardest qs i have answered.
Saladin:
Please post probs!
Navigation
[0] Message Index
[#] Next page
[*] Previous page
Go to full version