Twice as much soln of KMNO4 ws used for A ws as compared with B.
More the amount of KMNO4 required to complete the react means more no of moles of the substance(that is more conc )
More of it required for A, so A is more concentrated...
Get this right....conc of KMNO4 used is same for both....so the greater the volume of KMNO4 used, greater the conc of te conc of the substance