@ Burhan.arshad - OK PROBABLY THIS IS THE ANSWER..
Transition metal carbonates decompose faster because theyre not stable when heated.
the transition metals carbonates in the list are of zinc and copper.
Zinc is more reactive than copper, thus copper carbonate will get decomposed the fastest. = 25seconds = U
Next will be zinc = Z = 50seconds
Our of calcium magnesium and sodium, the reactivity is this like this-> Sodium, calcium , magnesium ...(sodium being the most reactive)
thus magnesium carbonate will decompose after copper and zinc...Magnesium carbonate = 100seconds = V
Then will be calcium carbonate = 300 seconds = X
and last will be of the most reactive metal sodium carbonate = Y = more than 1000seconds.